- 作者: 周善行 ; 盛暉鐸
- 作者服務機構: 輔仁大學化學系
- 中文摘要: The reactions of a new cationic complex, [ Cp(CO)/sub 2/Mo(.eta./sup 4/-2-methyl-3-SPh-C/sub 4/H/sub 4/) ]/sup +/PF/sub 6//sup -/ (3), with carbon, hydride, and nitrogen nucleophiles were found to give only the C-1 addition products in good yield. The X-ray crystal structures of two of the addition products 4a and 4e confirm the regio- and stereochemistry of the nucleophilic additions.
- 英文摘要: --
- 中文關鍵字: Butadiene Molybdenum Complex; Nucleophilic Addition Reaction; Stereo Control Chemistry; Unsymmetrical Distribution
- 英文關鍵字: 仁烯鉏錯合物;親核性加成反應;立體控制化學;非對稱分布