- 作者: 丁陳漢蓀
- 作者服務機構: Department of Chemistry and Chemistry Research Center, National Taiwan University, Taipei, Taiwan
- 中文摘要:
The polarized Raman spectrum in crystalline anthracene is recorded using an Ar+ laser as the light source. With the polarization data, empirical criteria of assigning molecular vibrations to Ag and B3g representations are derived. These criteria are discussed in the light of the theory developed in part I of this series.1
The lack of vibrational exaction structures in the spectrum of anthracene crystal is the strongest evidence to discredit the conventional polarizability theory and to support the theory presented in Part I.
The assignments of 11 Ag and 9 B3g vibrations in anthracene-h10, and also 12 Ag and 7 B3g vibrations in anthracene-d10 are reported. - 英文摘要: --
- 中文關鍵字: --
- 英文關鍵字: --