- 作者: 梁碧峰; 鍾崇燊
- 作者服務機構: Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300
- 中文摘要: In order to investigate the electrostatic and steric effects attributable to ligand cyclization, the kinetics of Cu(II) reacting with rac-5, 7, 7, 12, 14, 14-hexamethyl-1, 4, 8, 11-tetra-azacyclotetradecane(I) in acidic aqueous or alcohol-water media have been examined at 25.0° and μ=0.1 M in the presence and absence of anionic ligand using pH-stat techniques. Possible mechanism for the reaction is considered and second-coordinate-bond formation is proposed as rate-determining step.
- 英文摘要: --
- 中文關鍵字: --
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