- 作者: 許拱北; 張秋金
- 作者服務機構: Department of Chemistry, National Cheng Kung University, Tainan, Taiwan 70101, R.O.C.
- 中文摘要: N,N-bis(3,5-dimethylpyrazol-1-yl)methane (H/sub 2/CPz'/sub 2/) reacts with the hexacarbonyls of chromium, molybdenum, and tungsten to give cis-(H/sub 2/CPz'/sub 2/)M(CO)/sub 4/ derivatives with M=Cr, Mo, W. The direct allyl bromination of these complexes is also investigated and only the molybdenum complex is converted into (H/sub 2/CPz'/sub 2/)Mo(CO)/sub 2/(.pi.-C/sub 3/H/sub 5/)(Br).
- 英文摘要: --
- 中文關鍵字: Synthesis; allyl bromination; N,N-bis(3, 5-dimethylpyrazol-1-yl)methane derivatives of the group VI metal carbonyls
- 英文關鍵字: Synthesis; allyl bromination; N,N-bis(3, 5-dimethylpyrazol-1-yl)methane derivatives of the group VI metal carbonyls