• 作者： Chiang, Wen-Yen; Kuo, Meng-Ch'ang
• 中文摘要： 本研究乃係合成順丁烯二酐及丙烯兩者接枝聚乙烯醇之共聚合物,並將接枝共聚合之產物製成高分子導電薄膜。此種導電性薄膜之製法有二:(1)混合法,(2)浸漬法。經由此二種方法可製得含各種不同金屬鹽之複合薄膜,再經由NaBH/sub 4/水溶液還原成含各種不同金屬之金屬化薄膜,用來測其導電性及其他物性。並以 NH/sub 2/OH-HCl對PVA-g-AN/MA薄膜上之-CN基進行反應,以導入含amidoxime官能基,以增加薄膜螯合,並推測其可能結構。
• 英文摘要： Acrylonitrile (AN) and maleic anhydride (MA) were grafted onto PVA to form PVA-g-AN/MA membrane, which was reacted with different metal salts. PVA-g-AN/MA metal chelated films were prepared by the mixing and soaking methods. The electroconductivity of the resulting films was investigated. The amidoxime group was introduced into the PVA-g-AN/MA film under various conditions, in order to increase the amount of ions adsorbed in the soaking method.
• 中文關鍵字： 接枝共聚合物; 聚乙烯醇; 丙烯/馬來酐接枝共聚合物; 電導性; 光導性; 金屬螯合薄膜
• 英文關鍵字： Graft Copolymer; Polyvinyl Alcohol; Acrylonitrile/Maleic Anhydride Graft Copolymer; Electroconductivity; Photoconductivity; Metal Chalated Film