- 作者: 黃鎮台; 張幼香
- 作者服務機構: 國立清華大學化學系
- 中文摘要: 本文提出一使用 SGFM/II 的新方怯,此新法係利用提取標度格林函數的指數因子,以減低它隨時間改變的速率,與以往 BDF 法比較的結果顯示,此新法的適用範圍遠超過前者。
- 英文摘要: A new method of implementing the SGFM/II of sensitivity analysis [J.-T. Hwang, Proc. of NSC,R.O.C.,6(1), 37 (1982)] was developed. The method is based on extracting the exponential factors fromthe scaled Green's function matrix G, thereby reducing the rapidity in time variation of G. When compar-ed with the standard backward differentiation formula used in earlier studies, the present procedure enjoysa much broader applicability region as illustrated by an application to the nitrous oxide decompositionmechanism. A brief sensitivity analysis on the N O system also revealed an errorneous conclusion reachedbefore by Monat et al. concerning the dependence of[NO] upon elementary rate coefficients.
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