- 作者: 陳琪,蘇昶維,葉俊葳,胡慧玲,陳志德,王如春
- 作者服務機構: Department of Chemistry, Chung-Yuan Christian University, Chung-Li, Taiwan, R.O.C.
- 中文摘要: The reaction of N,N¢-di(2-pyridyl)formamidine (HDpyF) with MnCl2×4H2O afforded the complex MnCl2(HDpyF), which was characterized by X-ray crystallography. The HDpyF ligand chelates to the Mn(II) center through the first and the third nitrogen atoms to form a six-membered ring, leaving the second and the fourth nitrogen atoms uncoordinated. The HDpyF ligand is crystallographically disordered such that two different molecules can be solved. The neutral HDpyF ligand adopts the new s-cis-syn-s-trans conformation.
- 英文摘要: --
- 中文關鍵字: Disorder; Conformation; X-ray structure; N,N¢-di(2-pyridyl)formamidine.
- 英文關鍵字: --