- 作者: 周善行 ; 徐健宏
- 作者服務機構: 輔仁大學化學系
- 中文摘要: Hydride abstraction of tricarbonyl [ .eta./sup 4/-1-(phenylthio)-1,3-cyclohexadiene ] iron(0) with Ph/sub 3/ C/sup +/PF/sub 6//sup -/ regiospecifically provided the title compound (3) in excellent yield. Cationic complex (3) could react with a variety of nucleophiles in good yield. Hard nucleophiles prefer to attack at the C-1 position, whereas soft and hindered nucleophiles favor attack at the C-5 position. Some synthetic applications were also studied.
- 英文摘要: --
- 中文關鍵字: Iron Complex; Diene; Nucleophilic Addition Reaction
- 英文關鍵字: 鐵錯合物;雙烯;親核性加成反應