- 作者: Gialih Lina,bChing-Ing Hwanga, Ju-Yueh Chouhwanga and Hou-Jen Tsaic
- 中文摘要: A novel scale of steric substituent constant EsD is defined from the correlation of the logarithms of the internal rotation rate (kr) at 393 K with Hancock (Esc) steric constant by means of dynamic NMR. In the inhibition of Pseudomona species lipase by 2,2¢-bis-(N-substituted carbamoylmethyl)biphenyls (1-8), the logarithms of bimolecular rate constants are multiply correlated with both the Taft substituent constant s* and EsD.
- 英文摘要: --
- 中文關鍵字: --
- 英文關鍵字: --