- 作者: 張志強
- 作者服務機構: 成功大學化學系
- 中文摘要:
The homonuclear diatomic molecules are the simplest systems having both the .sigma. framework and the lone pair orbitals n/sub a/ and n/sub b/ for investigating their through space and through bond interaction. The striking orbital energy order n/sub g/.sim.n/sub a/+n/sub b/>n/sub u/.sim.n/sub a/-n/sub b/ has been accounted for by the through bond interaction. However, when the p-content in the lone pair orbitals n/sub a/ and n/sub b/ decreases, one may have the reverse orbital energy order: n/ sub g/
- 英文摘要: --
- 中文關鍵字: Space Interaction; Bond Interaction; Localized Molecular Orbital; Canonical Molecular Orbital
- 英文關鍵字: 空間交互作用;鍵交互作用;定域化分子軌域;正規分子軌域