- 作者: 郭悅雄 ; 林雲蓮 ; 王英基 等
- 作者服務機構: 台灣大學化學系
- 中文摘要: 8-Cedren-14-ol was oxidized with PCC, followed by autoxidation to yield 8,14-cedranolide and 8-cedren-14- carboxylic peracid. 8.beta.-Hydroxycedran-13-al was subjected to autoxidation in three different solvents to give eight products, from which the transformation from cedrane skeleton to noracorane and decahydroazulene skeletons were observed. A free radical pathway was proposed.
- 英文摘要: --
- 中文關鍵字: Autoxidation; Free Radical Reaction; Skeletal Rearrangement; Decahydroazulene; 8.Beta.-Hydroxycedran-13-Al; Noracorane
- 英文關鍵字: 自氧化;自由基反應;骨架重排;十氫薁