- 作者: 林金全
- 作者服務機構: 台灣大學化學系
- 中文摘要: The review is divided into four sections. We first consider the varied behavior of K n/sup 2/S and n/sup 2/D states in their chemical reactivity and physical characterization. We review the effect of orbital alignment of an electronically excited metal atom on the cross section of energy transfer or chemical reaction, and report the technique of a single supersonic jet employed to measure this effect on the Ca spin-changing collision. We discuss the effects of temperature and isotopic mass on the distribution of rotational quantum number of the product MgH to identify the reaction mechanism of Mg(/sup 1/P/sub 1/)+H/sub 2/. The final concerns are the quantum yield, fine-structure branching ratio and rate of collisional mixing for the K / sup 2/P/sub J/ doulets following photodissociation of KI at 193nm.
- 英文摘要: --
- 中文關鍵字: Dynamics; Kinetics; Metal Atom; Orbital Alignment; Photodissociation; Single Supersonic Jet; Temperature Effect
- 英文關鍵字: 動力學;動力學;金屬原子;軌域排列;光分解;單一超音速噴射;溫度效應