• 作者： Wan,Haewi-H.; Cheh,Huk-Y.
• 中文摘要： 在考慮質量傳遞及電極反應雙重情況下之電化學系統設計需要對電流分佈具有確實之了解。本文主旨乃是發展一數學模式和模擬方法來計算脈波電壓下之電流分佈。實驗操作則是在一旋轉圓盤電極及硫酸銅/硫酸所組成之電解槽中進行,其結果與理論計算甚為吻合。
• 英文摘要： The effective design and application of electrochemical systems requires an adequate understanding of current distribution in the presence of mass transfer and electrode reactions. In this investigation, a mathematical model as well as the numerical strategies for current distribution problems under pulsed potential conditions are developed. Experimental studies based on copper deposition in a copper sulfate-sulfuric acid system are carried out on a rotating disk electrode. Satisfactory agreements are obtained between experimental and theoretical results.
• 中文關鍵字： 脈波電壓; 電流分佈; 旋轉圓盤電極; 週期性電解
• 英文關鍵字： Pulsed Potential; Current Distribution; Rotating Disk Electrode; Periodic Electrolysis