- 作者: 吳永明 ; 楊曉萍 ; 薛峰 ; 麥松威 ; 黃乃正
- 作者服務機構: Department of Chemistry, The Chinese University of Hong Kong
- 中文摘要: 4-Trimethylsilyl-3(2H)-furanone (4) was converted to 4-trimethylsilyl-3-furyl triflate (5). An attempted generation of 3,4-didehydrofuran (3a) from 5 was unfruitful. On the other hand, 3,4-bis (trimethylsilyl) furan (6) was also converted to 4- trimethylsilyl-3-furylphenyliodonium triflate (7c) and its fluoride-promoted elimination pathway might involve a biradical intermediate 3b.
- 英文摘要: --
- 中文關鍵字: 3,4-Didehydrofuran; 4-Trimethylsilyl-3-Furyl Triflate; 3,4-Bis(Trimethylsilyl)Furan; 4-Trimethylsilyl-3-Furylphenyliodonium Triflate; Biradical
- 英文關鍵字: 3.4-雙去氫喃;4-3甲基矽烷-3-喃;3.4-二(三甲基矽烷)喃;4-三甲基矽烷-3-喃