- 作者: 鄭惠娟 ; 方俊民
- 作者服務機構: 台灣大學化學系
- 中文摘要: Aminomalononitrile reacted with conjugated carbonyl compounds to give 3H-pyrrolines. Treatment of 2-chloro-2- phenylthioacetonitrile with alkenes in the presence of potassium t-butoxide afforded 1- phenylthiocyclopropanecarbonitriles, which reacted with nucleophiles in 1,2-, 1,4- or 1,6-addition modes. The 1,2- adducts (cyclopropylimines) rearranged in situ to give substituted pyrroles.
- 英文摘要: --
- 中文關鍵字: Pyrrole Derivative; Aminomalononitrile; Rearrangement; Addition Reaction
- 英文關鍵字: 咯衍生物;胺基丙二;重排;加成反應