- 作者: 陳登海 ; 姜宏哲
- 作者服務機構: 台灣師範大學化學系
- 中文摘要: Reaction of dihydroxo (2,2'-iminodiethanolato-N,O,O') germanium(IV) or dihydroxo (2,2'-methyliminodiethanolato- N,O,O') germanium(IV) with bidentate ligands, e.g. diol,.alpha.-hydroxy acid, oxalic acid, 2,6-pyridinedicarboxylic acid, or 2-aminophenol in a mixture of ethanol and xylene mixture yielded a series of unsymmetrical spiro-germanium complexes. These complexes were characterized by NMR, IR, mass spectra and elementary analysis. The /sup 1/H NMR spectrums of all these compounds show the existence of an intramolecular N-Ge bond. X-ray analysis of compound 6 shows a short N-Ge bond (2.08.ANG.).
- 英文摘要: --
- 中文關鍵字: Germanium; Diethanol Amine; Spirocyclic Germanium Complex; Synthesis; Characterization
- 英文關鍵字: 鍺;亞胺二乙醇;螺環鍺錯合物;合成;特性