- 作者: 武克忠, 劉曉地, 李建玲
- 作者服務機構: College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang 050016, P. R. China
- 中文摘要: Nonisothermal kinetics of the solid-solid phase transition in (n-C10H21NH3)2ZnCl4(C10Zn), (n-C16H33NH3)2ZnCl4(C16Zn) and their binary system were determined by Kissinger and Ozawa methods from DSC measurements. The activation energy Ea of the binary system shows a waving dependence on WC10Zn%, which is caused by not only an intermediate (C10H21NH3)(n-C16H33NH3)ZnCl4 but also three solid solution ranges (α, β, γ,) in the phase diagram of C10Zn-C16Zn. The variations of the layer d-spacing are also convenient for the above result.
- 英文摘要: --
- 中文關鍵字: Bis(n-alkylammonium)tetrachlorometallates(II); Kinetic; Solid-solid phase transition; Activation energy; Energy storage.
- 英文關鍵字: --