- 作者: 陳蕙生; 陳秋炳
- 作者服務機構: Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan
- 中文摘要: Nitrosobenzene (NB) and nitroso-tetr-butane (NtB) were used to trap the photogenerated rhenium pentacarbonyl radical. Self trapped radicals and spin adducts were studied in detail by EPR spectroscopy. In methylene chloride, both nitroxide and anilino spin adducts can be observed with NtB at -30.degree.. In contrast, only the nitroxide spin adduct of nitrosobenzene was observed in either hexane or methylene chloride solution. This solvent controlled spin adduct chemistry, can be explained in terms of the solute-solvent interaction.
- 英文摘要: --
- 中文關鍵字: Spin Trap; pentacarbonylrhenium radical; nitrosobenzene; nitroso-t-butane; anilino spin adduct; nitroxide.
- 英文關鍵字: Spin Trap; pentacarbonylrhenium radical; nitrosobenzene; nitroso-t-butane; anilino spin adduct; nitroxide.