- 作者: 鄭秀瑤
- 作者服務機構: Department of Chemistry, Tunghai University, Taichung, Taiwan, R.O.C.
- 中文摘要: The bifurcation analyses of the internal rotation of three different series of monorotor molecules are investigated in this paper. Our results indicate that the types of catastrophe and topological regions are related to the generic form of potential energy function and the critical points. Namely, when the double-barrier energy function is represented as the third-order generic polynomial of the reduced reaction coordinate, the process is isomorphic to the elementary fold catastrophe. Similarly, when the triple-barrier energy functions are represented as the fourth-order generic polynomial of the reduced reaction coordinate, the process is isomorphic to the elementary cusp catastrophe.
- 英文摘要: --
- 中文關鍵字: Catastrophe theory; Bifurcation; Bithiophene; Bipyrrole; Fold catastrophe; Cusp catastrophe.
- 英文關鍵字: --