- 作者: 江詩富 ; 吳英彥 ; 陳志德 ; 耿台鈞 ; 王如春
- 作者服務機構: 中原大學化學系
- 中文摘要: The reaction of Mo/sub 2/(O/sub 2/CCF/sub 3/)/sub 4/ with (CH/sub 3/)/sub 3/SiI and PPh/sub 3/ gave the title complex [Mo/sub 2/(O/sub 2/CCF/sub 3/)/sub 2/I/sub 4/]-(HPPh/sub 3/)/sub 2/ which was characterized by X-ray crystallography. Crystal data for [Mo/sub 2/(O/sub 2/CCF/sub 3/)/sub 2/I/sub 4/](HPPh/sub 3/)/sub 2/:space group P.lbar., a = 10.953(4) .ANG., b= 12.784(3) .ANG., c= 19.829(4).ANG., .alpha.= 100.68(2).degree., .beta.= 91.16(2).degree., .grmma.= 112.98(2).degree., V = 2498.6(10) . ANG./sup 3/, Z=2, with final residuals R = 0.0887 and Rw = 0.0965. There are two independent molecules in each asymmetric unit. The molybdenum, oxygen, and fluoride atoms in one of the two independent molecules are disordered, such that the primary set is 53% occupied, and the secondary set 47%.
- 英文摘要: --
- 中文關鍵字: Quadruple Bond; Disordered System; Acetate Ligand
- 英文關鍵字: 四重鍵;無序系統;醋酸配位基