- 作者: 張儀尊; 余瑞錦
- 作者服務機構: Contribution from the Deparment of Chemistry, National Taiwan University
- 中文摘要: The reaction between p-bromophenylmagnesium bromide, p-bromomagnesiophenylmagnesium bromide and cyclohexanone has been reinvestigated. By using ammoniacal solution of ammonium chloride todecompose the resulting organomagnesium complex, we were able to improve the yield of one of the reaction products, and to isolate one product heretofore missing. The yield of 1'4'-dihydroxydicyclohexylbenzene based on p-dibromobenzene was increased to about 5%. Besides, we succeeded in isolating p-bromophenyl-cyclohexanol-1 which was so liable to undergo dehydration that previous workers had failed isolate.
- 英文摘要: --
- 中文關鍵字: --
- 英文關鍵字: --