- 作者: 趙琦華、王慶華、方瑞斌
- 作者服務機構: School of Pharmacy, Yunnan University, Kunming, 650091, P. R. China
- 中文摘要: A novel cyan-bridged macrocyclic nickel complex [{NiL1}{Fe(bipy)(CN)4}]2·5H2O 1 (L1 = 3,10-dimethyl-1,3,6,8,10,12-hexaazacyclotetradecane, bipy = 2,2-bipyridine) was synthesized and structurally characterized. The complex exhibits one-dimensional zigzag chain structures. Each ferrous(II) ion connects two nickel(II) ions using two trans CN- groups, and the remaining CN- groups are terminal. Magnetic measurement shows weak ferromagnetic interaction between the nearest Ni(II) ions through the diamagnetic Fe(II) ion.
- 英文摘要: --
- 中文關鍵字: Crystal structure; Magnetism; Cyano-bridged complex; Macrocyclic nickel complex.
- 英文關鍵字: --