- 作者: 王志偉 ; 黃文樞 ; 劉文宗
- 作者服務機構: 中山大學化學系
- 中文摘要: The direct reaction of iron pentacarbonyl with diethylamidocyclohexadiene gave three isomeric tricarbonyliron complexes, 1, 2 and 3. Only 1 isomerized to give 2 under acidic conditions, whereas 3 remained unchanged. The chemical properties of the tricarbonyl(amidocyclohexadiene)iron complexes differed from those of the tricarbonyl(carboxycyclohexadiene)iron complexes. Complex 3 which underwent no hydride abstraction with triphenylmethyl hexafluorophosphate, has an exo stereochemistry.
- 英文摘要: --
- 中文關鍵字: Tricarbonyl(Dialkylamidocyclohexa-1,3-Diene)Iron; Isomerization; Stereochemistry
- 英文關鍵字: 三羰基(二烷基氨基環己-1;3-二烯)鐵;異構化;同分異構形成;空間化學