- 作者: Ogilvie, J.F.
- 作者服務機構: 中央研究院原子與分子科學研究所
- 中文摘要: Analysis of measurements of vibration-rotational transitions of /sup 209/Bi/sup 1/H and /sup 209/Bi/sup 2/H in electronic ground state X 0/sup +/ yielded values of coefficients of radial functions that represent the internuclear potential energy and adiabatic and nonadiabatic rotational effects of the hydrogen atomic center. Both these effects have exceptionally large magnitudes, tentatively attributed in part to interaction with nearby electronically excited state A 1. The maximum range of validity of radial functions of BiH is 1.49.ltoreq.R/10/sup -10/m.ltoreq.2.4; the equilibrium internuclear distance R/sub e/ is(1.8041955.plmin.0.00000186)*10/sup -10/m.
- 英文摘要: --
- 中文關鍵字: Vibration-Rotational Spectra; Internuclear Potential Energy; Nonadiabatic Rotational Effect; Radial Function; Internuclear Distance
- 英文關鍵字: 振動轉動光譜;核間位能;非絕熱轉動效應;放射函數;核間距