- 作者: 李松軍, 鄭明霞, 張建明
- 作者服務機構: Key Laboratory of Pesticide & Chemical Biology of the Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China
- 中文摘要: This article presents an original work aiming at kinetically surveying the substrate-selective mechanism from a molecularly imprinted polymer. With Bisphenol A (BPA) as the template, the imprinted polymer was prepared. The result indicates that the imprinted polymer presents a much more complicated sorption toward the template than toward its analogue. The rate constant in the case of the template appears to be a function of coverage degree. There are also significant deviations from the idealized Langmuir model. Related information indicates that these logically can be a result from the induced molecular memory within the binding framework, which makes the polymer capable of selectively adsorbing the imprint species.
- 英文摘要: --
- 中文關鍵字: Molecularly imprinted polymer; Adsorption; Kinetics.
- 英文關鍵字: --