- 作者: 陳國美,陳光前,楊宗航
- 作者服務機構: Department of Chemistry, National Sun Yat-sen University, Kaohsiung, Taiwan, R.O.C.
- 中文摘要: A quantum treatment on ICN photodissociation from an initial parallel transition (Ω' = 0 ← Ω" = 0) to the asymptote CN(|Σ+, JMN 〉) + I(2P1/2) is presented. Density matrices of both photofragments are derived, and explicit expressions of the state multipoles in terms of the angular momentum coupling coefficients and the rotation-bending factors have been obtained. The present theoretical framework provides a foundation to study photofragments with non-null electronic and/or spin angular momenta. To investigate the angular momentum polarizations phenomena, these density matrices can play a prime role in laser-based detections of state-selected photofragments.
- 英文摘要: --
- 中文關鍵字: ICN photodissociation; Density matrices; State multipoles
- 英文關鍵字: --