- 作者: 林曦 ; 劉陵崗
- 作者服務機構: 彰化師範大學化學系
- 中文摘要: The reactions of tris(acetonitrile) tricarbonylchromium (1) with trimethylsilyl derivatives of phenalene, indene, 1,2-dihydronaphthalene and trans-.beta.-methylstyrene gave products respectively, containing no trimethylsilyl groups. The reactions of (1) with trimethylsilyl derivatives of benzene, toluene and cycloheptatriene gave products, respectively, containing trimethylsilyl groups. The reaction of (1) with 1,2-bis(trimethylsilyl-1,2-dihydro)naphthalene gave product in which only trimethylsilyl at the allylic position was cleaved. Compound (10) crystallizes in the orthorhombic system, space group Pbca, with a=12.228(4), b=14.288(1), c=15.128(3).ANG., Z=8, R/sub F/=0.046, and R/sub w/=0.047. X-ray crystallographic data confirm that the Cr(CO)/sub 3/ moiety is bonded to phenalene in a .eta./sup 6/-mold.
- 英文摘要: --
- 中文關鍵字: Trimethylsilyl Derivative; Phenalene; Indene; Reaction
- 英文關鍵字: 三甲基亞矽烷基衍生物;萉;;反應