- 作者: 林曦 ; 陳彥賢
- 中文摘要: The reactions of R/sup 1/R/sup 2/CpM(CO)/sub 3//sup -/ Li/sup +/ (M=Mo, W) with .alpha.,.alpha.'-dichloro-p-xylene yielded p-xylyl bridged dinuclear complexes of R/sup 1/ R/sup 2/CpM(CO)/sub 3/ in high yields. All of such new complexes are very stable to air and water. Some of them are stable even in dilute acids and dilute bases. Complex 4 crystallizes in the mono-clinic system, space group P2/sub 1//n, with a=6.847(5).ANG., b=9.838(2).ANG., c=25.140(10).ANG., .beta.=96.56(5).degree., Z=2, R/sub F/=0.077, R/sub w/=0.105 and V=1682.4(14).ANG./sup 3/.
- 英文摘要: --
- 中文關鍵字: Molybdenum; Tungsten; Xylene Dinuclear Complex
- 英文關鍵字: 鉬;鎢;二甲苯雙核錯合物