• 作者： Chou, Chih-Hsiung; Lee, Min-Dar; Chen, Yan-Ping
• 中文摘要： 本文提供丙醛,3-甲基-2-丁酮與1-丁醇在760mmHg下之氣液相平衡數據。所有二成分系的實驗數據符合熱力學一致性的測試。這些二成分系數據被運用來求取Wilson,NRTL和 UNIQUAC液相模式的最佳參數。直接由UNIQUAC液相模式,最佳參數來進行三成分系氣液相平衡之估算,得到滿意之結果。
• 英文摘要： Vapor-liquid equilibrium (VLE) data were reported for the binary and ternary mixtures of propionaldehyde, 3-methyl-2-butanone and 1-butanol at 760mmHg. Thermodynamic consistency tests showed that all binary data were acceptable. These binary data were used to correlate the optimal binary parameters of the Wilson, NRTL and UNIQUAC liquid models. Prediction of ternary VLE behavior from the UNIQUAC model with best-fitted parameters from binary experimental data also indicated satisfactory results.
• 中文關鍵字： 氣液相平衡; 熱力學一致性; 液相模式; 丙醛; 3-甲基-2-丁酮; 1-丁醇
• 英文關鍵字： Vapor-Liquid Equilibria; Thermodynamic Consistency; Liquid Model; Propionaldehyde; 3-Methyl-2-Butanone; 1-Butanol