- 作者: 林漢鎮 ; 林昀輝 ; 陳志鴻 等
- 作者服務機構: 宜蘭農工化學工程科
- 中文摘要: Solid-state /sup 13/C CP/MAS spectral analysis of the hydrolysis products of Sn(OAc)/sub 4/ allowed the hydrolysis intermediates, Sn(OH)(OAc)/sub 3/, Sn(OH)/sub 2/(OAc)/sub 2/ and Sn(OH)/sub 3/(OAc), to be identified. The results show that the hydrolysis consists of three steps; the first and second steps are consecutive reactions and the third is reversible. Intermolecular exchange between hydrolysis products, i.e. Sn(OAc)/sub 4/, Sn(OH)(OAc)/sub 3/, Sn(OH)/sub 2/(OAc)/sub 2/ and Sn(OH)/ sub 3/(OAc), and acetic acid was observed from the measurement of /sup 1/ H and /sup 13/C solution spectra at varied temperatures in CD/sub 2/Cl/sub 2/ with .DELTA.G/sup .dbldag.//sub 248/ 50.5kJ/mol.
- 英文摘要: --
- 中文關鍵字: Hydrolysis; Sn(Oac)/Sub 4/; Carbon-13 Nmr Spectroscopy; Tin Compound; Intermolecular Exchange; Nmr
- 英文關鍵字: 水解;四醋酸錫;碳13核磁共振光譜法;錫化合物;分子間交換;核磁共振