- 作者: --
- 作者服務機構: Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Iran
- 中文摘要: An efficient and mild methodology for the oxidation of primary and secondary alcohols to the corresponding carbonyl functions is described with N,N,N',N'-tetrabromobenzene-1,3-disulfonamide and poly(N-bromobenzene-1,3-disulfonamide) using microwave irradiation under solvent-free conditions. Aliphatic, benzylic and allylic alcohols are rapidly oxidized without over-oxidation to carboxylic acids. Secondary carbinols are slowly oxidized so that the reaction is highly chemoselective.
- 英文摘要: --
- 中文關鍵字: Oxidation; Alcohols; Solid state; Microwave; TBBDA; PBBS.
- 英文關鍵字: --