- 作者: 易光輝, 王曉芬, 李錦祥
- 作者服務機構: Department of Applied Cosmetology, Hungkuang University, Shalu, Taichung 433, Taiwan, R.O.C.
- 中文摘要: Treatment of Pd(PPh3)4 with 2-bromothiazoline, BrCSCHCHN, in dichloromethane at -20 °C causes an oxidative addition reaction to produce the palladium complex [Pd(PPh3)2(η1-CSCHCHN)(Br)] 2 by substituting two triphenylphosphine ligands. In dichloromethane complex 2 at room temperature for 8 h, it undergoes displacement of the triphenylphosphine ligand to form the dipalladium complex [Pd(PPh3)Br]2(μ,η2-CSCHCHN)2 3 in which the two thiazoline ligands coordinated through carbon to one metal center and bridged the other metal through nitrogen atom. Complexes 2 and 3 are characterized by X-ray diffraction analyses.
- 英文摘要: --
- 中文關鍵字: Thiazoline ligand; Palladium; Dipalladium; Nitrogen-assisted; X-ray diffraction.
- 英文關鍵字: --