- 作者: Alexander N. Tarnovsky, Magnus Wall, Marcus Rasmusson, Torbjorn Pascher and Eva Akesson
- 中文摘要: We have studied the photodissociation dynamics of chloroiodomethane (CH2ICl) in acetonitrile by ultrafast pump-probe spectroscopy. The reaction was initiated using a femtosecond pulse at 266 nm and the transient absorption was measured out to delays of 300 ps over a spectral region from 330 to 850 nm. The photodissociation leads to formation and subsequent vibrational cooling of a product species, which we suggest is the isomer of chloroiodomethane, CH2Cl-I, likely produced via in-cage recombination between the nascent fragments CH2Cl and I.
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