- 作者: 周善行、陳婷菀
- 作者服務機構: Department of Chemistry, Fu Jen Catholic University, Taipei, Taiwan 242, R.O.C.
- 中文摘要: 3-Phenylthio-3-sulfolene (1) was readily converted to a C-5 substituted product 2, which upon thermolysis and complexation with Fe2(CO)9 gave (η4-diene)iron complexes 3a and 3b. Treatment of 3a and 3b with aq. HPF6 and Ac2O provided the title compound 5, which reacted regio- and stereospecifically with some nucleophiles to give the addition products 3b and 7.
- 英文摘要: --
- 中文關鍵字: 3-Sulfolenes; (η4-Diene)iron complexes; (η5-Dienyl)iron complexes; Nucleophilic addition reactions.
- 英文關鍵字: --