- 作者: Yuh-Wern Wu*, Ming-Dar Chen and Jyh-Ferng Yang
- 作者服務機構: Chemical Engineering Department, I-Shou University, Ta-Hsu, Kaohsiung 84008, Taiwan, R.O.C.
- 中文摘要: The concerted mechanism of free radical SH2' reaction of 2-substituted allyl chloride was suggested again by inverse secondary α-deuterium isotope effect. The transition state of free radical SH2' reaction of allyl chlorides seems to be symmetrical and is not as early as that of a free radical addition reaction.
- 英文摘要: --
- 中文關鍵字: Free radical SH2' reaction; Concerted mechanism; Inverse secondary α-deuterium isotope effect; The structure of transition state.
- 英文關鍵字: --