• 作者： 黃建和; 鄭華生
• 作者服務機構： Institute of Chemistry, Tsing Hua University, Hsinchu
• 中文摘要： Mӧssbauer and ir spectroscopies have been applied to the study of radiation effect on Fe..X(CN)5 (X=NO+, NH3, H2O, NO2¯, SO,=) and Fe…X(CN)5(X=NH2, H2), NO2¯). FE(II) complexes were not oxidized to Fe(III), whereas FE(III) complexes were reduced to Fe(II). Na2[FeNH3(CN)5]‧H2O was partially reduced at 7 hour irradiation, but [FeNO(CN)5]= was obtained at the longer irradiations due to the replacement of H by O produced by water radiolysis.
• 英文摘要： --
• 中文關鍵字： --
• 英文關鍵字： --