- 作者: 葉明倉,曹文正,劉勤經
- 作者服務機構: Department of Chemistry, National Taiwan Normal University, Taipei 117, Taiwan, R.O.C.
- 中文摘要: Intramolecular Diels-Alder reaction (IMDA) precursors are easily available starting from addition of ester functionalized zinc-copper reagents to cyclohexadienyl- and cycloheptadienylirontricarbonyl cation salts. The resulting cyclic 1,3-dienes containing an a,b-unsaturated ester functionality underwent smoothly IMDA reaction to afford bridged tricyclic compounds. Bridged heterotricyclic skeletons were also available via IMDA reaction of cyclic 1,3-dienes bearing an imine or aldehyde functionality.
- 英文摘要: --
- 中文關鍵字: Cyclic 1,3-diene; Intramolecular Diels-Alder reaction; Bridged-tricyclic compound.
- 英文關鍵字: --