- 作者: 徐聖煦 ; 鄒先岩
- 作者服務機構: 清華大學化學系
- 中文摘要: The stereoselective synthesis of peperomin C is reported. The key steps include the stereoselective alkylation of the substituted diphenylmethyl group to the r-butyrolactone ring and transformation of the carbonyl group to the other side in the butyrolactone ring by reduction of the lactone carbonyl followed by degradative oxidation.
- 英文摘要: --
- 中文關鍵字: (+)-Peperomine; Butyrolactone; Stereoselectivity; Synthesis; Oxidation; Reduction
- 英文關鍵字: 丁內酯;立體選擇性;合成;氧化;還原