- 作者: 林志彪 ; 廖德琇
- 作者服務機構: 輔仁大學化學系
- 中文摘要: The synthesis of M(PR/sub 3/)/sub 2/Cl/sub 2/ (M=Pd and Pt, R=alkyl or aryl) from K/sub 2/MCl/sub 4/ (in H/sub 2/O) and PR/sub 3/ (in CH/sub 2/Cl/sub 2/) was promoted by the addition of phase-transfer catalysts (PTC). The greater the amount of PTC used, the more quickly the reaction completed. /sup 31/P NMR spectra of some M(PR/sub 3/)/sub 2/Cl/sub 2/ in the presence of free PR/sub 3/ were measured; these NMR results were used to explain problems encountered during the preparations.
- 英文摘要: --
- 中文關鍵字: Phase Transfer Catalyst; Phosphine Complex; Palladium; Platinum; Preparation
- 英文關鍵字: 相轉移觸媒;膦錯合物;鈀;鉑;製備