• 作者： 李世元 ; 曾喜樑 ; 潘安國
• 作者服務機構： 淡江大學化學系
• 中文摘要： Hexalkylditin is prepared by a Lewis acid-promoted(MgCl/sub 2/) reductive reaction of bis(trialkyltin) oxide using magnesium metal as reducing agent. Hexabutyl- and hexaphenylditin are synthesized with 95% and 80% yield separately and a radical mechanism is proposed for the reaction condition. Unsymmetric ditin, Bu/sub 3/Sn- SnPh/sub 3/, was first synthesized by this reductive method.
• 英文摘要： --
• 中文關鍵字： Hexaorganoditin; Triorganotin Oxide; Lewis Acid; Reduction
• 英文關鍵字： 六有機二錫；三有機錫氧化物；路易士酸；還原