- 作者: 葉文彥,李錦祥,彭旭明
- 作者服務機構: Department of Chemistry, National Sun Yat-Sen University, Kaohsiung 804, Taiwan, R.O.C.
- 中文摘要: Treatment of [Cu(pcho)2(NCMe)][BF4] 1 (pcho = 2-(diphenylphosphino)benzaldehyde) with aqueous H2O2 in THF solvent affords [Cu2(dpb)2(THF)2(H2O)2] [BF4]2 2 (dpb = 2-(diphenylphosphinoxide)-benzoate) after crystallization from diethyl ether. This reaction involves oxidation of Cu(I) to Cu(II) ion, phosphine to phosphinoxide, and benzaldehyde to benzoate species. The crystal structure of 2 consists of two copper(II) atoms bridged by two carboxylate moieties of the dpb ligands. The coordination about each copper(II) atom is a distorted trigonal bipyramid.
- 英文摘要: --
- 中文關鍵字: Cu(II) complex; 2-(Diphenylphosphinoxide)benzoate; 2-(Diphenylphosphino)benzaldehyde.
- 英文關鍵字: --