- 作者: 易光輝,李錦祥
- 作者服務機構: Department of Applied Cosmetology, Hungkuang University, Shalu, Taichung 433, Taiwan, R.O.C.
- 中文摘要: The first metal-carbon bond β-form paddlewheel complexes containing a Pd24+ core, [Pd(η2-dithio)]2(μ-dppa)(μ-SCNMe2) (dithio = S2P(Oet)2, 2; S2COEt, 3; S2CNC4H8, 4), were prepared by the reactions of the α-form paddlewheel-type Pd2+4 dipalladium complex [Pd2(μ-Hdppa)2(μ-SCNMe2)2][Cl]2, 1 with various dithio-ligands, [NH4][S2P(Oet)2], [K][S2COEt] and [NH4][S2CNC4H8], in methanol at ambient temperature (Hdppa = bis(diphenylphosphino)amine). Electronic spectra and two X-ray structures of the Pd2+4 species have been determined.
- 英文摘要: --
- 中文關鍵字: Metal-carbon bond; β-Isomer; Paddlewheel type; Dipalladinum; X-ray structures
- 英文關鍵字: --