- 作者: 易光輝、李錦祥、王瑜
- 作者服務機構: Department of Applied Cosmetology, Hungkuang University, Shalu, Taichung, Taiwan 433, R.O.C.
- 中文摘要: The η1-thiocarbamoyl palladium complexes [Pd(PPh3)(η1-SCNMe2)(η2-S2R)] (R = P(Oet)2, 2; CNEt2, 3) and trans-[Pd(PPh3)2(η1-SCNMe2)(h1-Spy)], 4, (pyS: pyridine-2-thionate) are prepared by reacting the η2-thiocarbamoyl palladium complex [Pd(PPh3)2(η2-SCNMe2)][PF6], 1 with (EtO)2PS2NH4, Et2NCS2Na, and pySK in methanol at room temperature, respectively. Treatment of 1 with dppm (dppm: bis(diphenylphosphino)methane) in dichloromethane at room temperature gives complex [Pd(PPh3)(η1-SCNMe2)(η2-dppm)] [PF6], 5. All of the complexes are identified by spectroscopic methods and complex 1 is determined by single-crystal X-ray diffraction.
- 英文摘要: --
- 中文關鍵字: Thiocarbamoyl; Palladium, Crystal structure; Dithiocarbamate; Phosphorodithioate ligand.
- 英文關鍵字: --