- 作者: 周善行 ; 余玉珠
- 中文摘要: A series of sulfur-substituted dienyl nitrones and oximes were conveniently prepared from the 3-sulfolene precursors. Regiospecific intramolecular 1,3-dipolar cycloadditions of nitrones and nitrile oxides with sulfur- substituted dienes have been efficiently carried out from the suitable 3-sulfolene precursors. The stereochemistry of the cycloaddition of nitrones depends on the structure of the substituent (sulfide or sulfone) on the diene as well as on the chain length connecting the diene and nitrone. The fused bicyclic products obtained from these reactions have been converted to some interesting heterocyclic compounds which have the useful structure of vinyl sulfide or sulfone.
- 英文摘要: --
- 中文關鍵字: Intramolecular Cycloaddition; Sulfur-Substituted Diene; Stereochemistry; Nitrone; 1,3-Dipolar Cycloaddition
- 英文關鍵字: 分子內環化加成;硫取代二烯;立體化學;硝酮;1;3-二極環化加成