- 作者: 黃承文; 高惠霖; 何世延
- 作者服務機構: Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300
- 中文摘要: The photochemistry of diazomethane in presence of hydrogen sulfide gas has been studied at 4358 and 3660-A. singlet methylene radicals react with hydrogen sulfide to from methanethiol which decomposes at lower pressures. The measured decomposition rate constants are 5.5×10.. and 9.6×10.. s¯1 in 4358 and 3660-A systems, respectively. Singlet methylene inserts into a S-H bond as 200 times fast as into a C-H bond.
- 英文摘要: --
- 中文關鍵字: --
- 英文關鍵字: --