- 作者: CHUNG-HSIN WU ; CHENG-FANG LIN ; SHANG-LIEN LO ; TATSUYA YASUNAGA
- 中文摘要: Kinetic research often is conducted using tradition methods of kinetic study, namely batch and flow methods. Reaction rate constants and reaction mechanisms, however, are difficult to determine using these methods because too many factors, such as mass-transfer, diffusion, adsorption, and desorption, occur simultaneously in a system. In addition, kinetic information from fast reactions cannot be easily detected. This review paper focuses on the pressure-jump technique, which detects any change in an equilibrium system due to a sudden pressure change, and hence, is able to illustrate the reaction mechanisms and calculate the rate constants. Pressure-jump applications in complex formation, hydrolysis, ion exchange, and adsorption/desorption are discussed in this paper.
- 英文摘要: --
- 中文關鍵字: kinetic study, adsorption, pressure-jump
- 英文關鍵字: --