- 作者: 周大紓 ; 周善行
- 作者服務機構: 中央研究院化學研究所
- 中文摘要: 3-Sulfolenes are easily converted to the corresponding 1,3-dienes by cheletropic removal of SO/sub 2/. In addition, the generation of 3-sulfolenyl anions are achieved under several reaction conditions. Therefore, 3-sulfolenes serve as butadienyl anion equivalents and this strategy has been applied to the preparations of substituted dienes and the total synthesis of natural products.
- 英文摘要: --
- 中文關鍵字: 3-Sulfolene; 3-Sulfolenyl Anion; Substitution Reaction; Substituted 1,3-Butadiene; Cheletropic Reaction; Natural Product Synthesis
- 英文關鍵字: 3-丁二烯;3-丁二烯基陰離子;取代反應;取代1;3-丁二烯;三環加成反應;天然物合成