- 作者: 林渭川
- 作者服務機構: Contribution from the Department of Chemistry, National Taiwan University, Taipei
- 中文摘要:
Proton magnetic resonance spectrum of 25% (volume) methyl 2,3-dubromopropionate in benzene exhibits a typical ABC patter in which the four strong lines from each nucleus can be immediately recognized. The assignment of spectral lines and the determination of energy-level diagram were thus straightforward.
Field-sweep spin decoupling experiment with respect to the other transition-square (with B spin kept at -1/2) of the sample was found to be in complete analogy with two-spin AX system. However, spin decoupling with respect to the inner transition-square (with B spin kept at +1/2) reveals a weak satellite line on each side of the decoupled A (or C) signal. These weak satellite lines are found to be due to JAB (or JBC) and may prove to be useful for the direct determination of JAB and JBC. - 英文摘要: --
- 中文關鍵字: --
- 英文關鍵字: --