- 作者: 楊登貴 ; 李東昇 ; 鄧宗凡 等
- 作者服務機構: 中興大學化學系
- 中文摘要: Introducing two chiral auxiliaries, sulfoxide and menthol, into an acrylate would have either matched or mismatched pair systems. The presence of chiral menthol in.alpha.-sulfinylacrylates can change the diastereoselectivity from 24% d.e. to a single diastereomer by manipulation of the double asymmetric strategy.
- 英文摘要: --
- 中文關鍵字: Asymmetric Diels-Alder Reaction; .Alpha.-Sulfinylacrylate; Double Asymmetric Induction; Chiral Reaction
- 英文關鍵字: 非對稱Diels-Alder反應