- 作者: 周大新
- 作者服務機構: 中央研究院化學研究所
- 中文摘要: The titled compounds are synthesized through multi- step sequences involving consecutive [ /sub .pi./4/sub s/+/sub .pi./2/sub s/ ] cycloadditions of norbornadiene with two units of chlorinated cyclopentadiene. A dyotropic double hydrogen migration was observed between two closely located double bonds during the process of aromatization of a cyclohexadiene moiety. A hydroxyl group is introduced onto either of the two methylene bridges in order to provide products suitable for solvolytic analyses.
- 英文摘要: --
- 中文關鍵字: Hydrogen Migration; Norbornadiene; Hexachlorocyclopentadiene; Cycloaddition; Decarbonylation; Laticyclic Topology; Isodrin
- 英文關鍵字: 氫移轉;去甲□二烯;六氯環戊二烯;環加成反應;去醯作用